domingo, 29 de abril de 2007

Modelo atómico

El modelo atómico actual resulta más complejo que sus predecesores, aunque sigue aceptando la existencia de un núcleo central (donde se concentra toda la masa) y de unos niveles o capas de energía en los que se encuentran los electrones. Recordar también que las órbitas de los electrones pueden ser circulares o elípticas.
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Dentro del átomo los electrones se están moviendo a gran velocidad del modo, que si se superponen varias fotografías que muestren la posición de uno de estos electrones en cada instante se obtendría lo que se ha dado en llamar nube electrónica.
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Para cada electrón, la nube electrónica no tiene la misma densidad en todo el átomo. Esto nos indica que el electrón se encuentra con más frecuencia en unos lugares que en otros. Definición:
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Se llama orbital (que es distinto del concepto de órbita) a la zona del átomo dentro de la cual hay una gran probabilidad de encontrar un electrón.
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Fig. Función de onda de un electrón de un átomo de hidrógeno. Las áreas brillantes corresponden a densidades de probabilidad elevadas de encontrar el electrón en dicha posición.

Los átomos poseen niveles de energía, que a su vez están formados por varios subniveles (órbitas muy próximas entre si, con muy pequeñas variaciones de energía).

Los niveles de energía se denotan por un número cuántico n=1,2,3,... y los subniveles por la notación: s, p, d, f..., que indica el número de orbitales en cada subnivel (s equivaldría a 1, p a 3, d a 5, y así de dos en dos). Dentro de cada nivel existe un número máximo de electrones que nos podemos encontrar, que viene dado por la expresión 2(n^2).

Cualquier orbital de tipo s se representa con una superficie esférica con centro en el núcleo. Los límites de esta superficie esférica definen la región del espacio para la cual la probabilidad de encontrar al electrón es elevada, generalmente superior al 75% en el subnivel s.

Las representaciones gráficas más comunes de los tres orbitales p son idénticas y consisten en dos esferas tangentes en el núcleo. La única diferencia estriba en la orientación de las mismas (según los ejes x, y o z). La probabilidad en este caso es también del 75%.

Las representaciones de los demás subniveles las podéis encontrar aquí.

MECÁNICA CUÁNTICA:

Y a partir de aquí surge la mecánica cuántica, conocida también como mecánica ondulatoria o física cuántica, que estudia el comportamiento de la luz y la materia a escalas atómicas. El concepto de partícula "muy pequeña" atiende al tamaño en el cual comienzan a notarse efectos como la imposibilidad de conocer con exactitud la posición de una partícula.


En este mundo, la materia puede estar en dos lugares al mismo tiempo; los objetos se comportan a la vez como partículas y como ondas (una extraña dualidad descrita por la ecuación de onda de Schrödinger), y nada tenemos seguro: el mundo cuántico funciona a base de probabilidades.


Más información en wikipedia o en el blog Sechura.

76 comentarios:

Tomas Coiro dijo...

Verdaderamente dificil

M'Kabi 3.14 dijo...

Muy bueno Sable. Verdaderamente muybien explicado y con un lenguaje comprensible

Anónimo dijo...

Gracias m'kabi. La intención era realizar una introducción fluida, y a partir de aquí comenzar a introducir conceptos curiosos, no por ello más complicados, de la teoría atómica de nuestros tiempos.

Sería bueno leerlo dos veces o acceder a los enlaces, varias veces tuve que hacerlo yo para redactar el artículo, pero si surge alguna duda concreta sabes koinor que estoy para ayudar en lo que se pueda. ;)

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Sable te quiero comentar algo que se me ocurrió al ver tu cita de la semana.
Recuerdo haber leido alguna vez que Einstein habia dicho esto en un examen:
Alumno:Profesor, este examen tiene las mismas preguntas que el del año pasado.
Einstein: si, pero las respuestas ya son otras.

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Esta entrada me ha recordado la física que dí hace unos años en bachiller. Si es una introducción a nuevos artículos tan interesantes como éste, los espero de buen grado

Anónimo dijo...

Aprovecho para contar una historia relacionada con la cita de koinor:

La teoría atómica nació en la Antiguedad clásica cuando se pensó que si se cogía un material y se le iba dando martillazos llegaría un momento en el que no se podría dividir más, y a eso lo llamaron átomo(de ahí el nombre).

Pero tras esto durante casi 20 siglos no hubo ningún avance en la teoría atómica. Hasta que en

1808, aparece el modelo de Dalton(muy simple),

pero a partir de aquí:

1897 modelo de Thomson
1911 modelo de Rutherford
1913 modelo de Bohr
1924 modelo de Schrodinger(actual)

Estos 28 años supusieron un avance importantísimo en el que cada año se producían nuevas correcciones y aportaciones, y como dice Einstein(1879-1955) los pensamientos, las ideas, los conocimientos, la ciencia, las RESPUESTAS cambiaban de un año a otro.

Por eso me alegra saber esa cita ya que es una forma de constatar esta revolución científica durante estas tres décadas. Gracias koinor.

Un http://www.grafologiamorettiana.it/apropositodi/albert-einstein.jpg
para todos.

Intentaré que los siguientes artículos sobre la teoría atómica sean de vuestro agrado. ;)

Un saludo!

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De nada

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